• Home
  • Research
    • Design of Energy Conversion Ma...
    • Development of in situ Surface...
    • Expansion of Synchrotron Radia...
    • Hot Papers
  • Publication
    • 2021-2025
    • 2016-2020
    • 2010-2015
    • 2009 and Before
  • Facilities
  • Members
    • Principal Investigator
    • Postdoctoral Fellows
    • Ph.D. Students
    • M.S. Students
    • Graduated Students
  • Join us

Congratulations to Hui Su and Chenyu Yang for their paper about Tensile straining of iridium sites in manganese oxides for proton-exchange membrane water electrolysers published on Nature Communications

发布者:张宇浩发布时间:2023-12-20动态浏览次数:15

Although the acidic oxygen evolution reaction (OER) plays a crucial role in proton-exchange membrane water electrolysis (PEMWE) devices, challenges remain owing to the lack of efficient and acid-stable electrocatalysts. Herein, we present a low-iridium electrocatalyst in which tensile-strained iridium atoms are localized at manganese-oxide surface cation sites (TS-Ir/MnO2) for high and sustainable OER activity. In situ synchrotron characterizations reveal that the TS-Ir/MnO2 can trigger a continuous localized lattice oxygen-mediated (L-LOM) mechanism. In particular, the L-LOM process could substantially boost the adsorption and transformation of H2O molecules over the oxygen vacancies around the tensile-strained Ir sites and prevent further loss of lattice oxygen atoms in the inner MnO2 bulk to optimize the structural integrity of the catalyst. Importantly, the resultant PEMWE device fabricated using TS-Ir/MnO2 delivers a current density of 500 mA cm−2 and operates stably for 200 h.


地址:No.42, Hezuo South Road Shushan District, Hefei, Anhui, 230029, P.R.China. 电话:0551-63602117Email:qhliu@ustc.edu.cn

Copright © 2020 lxafs.ustc.edu.cn All Right Reserved. 版权所有 中国科学技术大学能源转换与原位表征实验室制作维护